For starters, I'm guessing your value of 175(psi?) is your cylinder compression value?
Just keep in mind that this value IS NOT the compression ratio. If you want to calculate your compression ratio, and then work out how to increase it with a head skimming, then you need to take a number of measurements of your bore, stroke, dish and head volumes, piston crown to deck height, Crown to Ring land etc, HG Thickness and then calculate from there.
Compression ratio: a Volumetric function
Cylinder Pressure: a Pressure function
175 is sounds like a good healthy value. You should talk to your engine builder about how much planing you will need to increase comp ratio.